Inner Sanctum. Episode 45, The Wailing Wall. Two women are heavy into S & M. Their boyfriend? Who else but Boris Karloff himself. (November 6, 1945)
The Adventures of Philip Marlowe. Episode 14, The Orange Dog. Mix together the colors red and yellow, and you get orange. That takes care of the color part of the title. Not sure about the dog. Mixed breed? (January 22, 1949)